Amancio Amaro
9Goals for Spain
| October 19, 1972 | Spain 2–2 Yugoslavia | 30' |
| October 15, 1969 | Spain 6–0 Finland | 44' |
| April 30, 1969 | Spain 2–1 Yugoslavia | 27' |
| May 8, 1968 | Spain 1–2 England | 47' |
| July 15, 1966 | Spain 2–1 Switzerland | 75' |
| June 17, 1964 | Spain 2–1 Hungary | 112' |
| March 11, 1964 | Spain 5–1 Republic of Ireland | 29' |
| March 11, 1964 | Spain 5–1 Republic of Ireland | 12' |
| May 30, 1963 | Spain 1–1 Northern Ireland | 60' |