Marcelino Martínez
4Goals for Spain
| June 21, 1964 | Spain 2–1 Russia | 84' |
| March 11, 1964 | Spain 5–1 Republic of Ireland | 89' |
| March 11, 1964 | Spain 5–1 Republic of Ireland | 33' |
| November 23, 1961 | Spain 3–2 Morocco | 12' |
| June 21, 1964 | Spain 2–1 Russia | 84' |
| March 11, 1964 | Spain 5–1 Republic of Ireland | 89' |
| March 11, 1964 | Spain 5–1 Republic of Ireland | 33' |
| November 23, 1961 | Spain 3–2 Morocco | 12' |